It is used as a fumigant to sterilize facilities, foodstuffs, and medical equipment, but its major use is as a reactive intermediate in production of various chemicals including antifreeze, polyethylene fibers and bottles and non-ionic surface active agents, glycol ethers, ethanolamines and choline. ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C . 2 0 obj Ethylene oxide Safety Data Sheet P-4798 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Exposure to ethylene oxide may cause headache, nausea, vomiting, diarrhea, breathing difficulty, drowsiness, weakness, exhaustion, eye and skin burns, frostbite, and reproductive effects. OSHA has adopted the GHS and updated the Hazard Communication Standard in 2012. The EPA has set the upper level of acceptable cancer risk for polluted air at 1 in 100 in one million, or one in 10,000. Ethylene oxide (also known as ETO or oxirane) is a flammable gas with a somewhat sweet odor. NIOSH: The recommended airborne exposure limit … ACGIH Threshold Limit Values TLV OSHA has set exposure limits for employees working in facilities where ethylene oxide gas is present. It is obtainable mixed with carbon dioxide in the proportion of one part ETO to nine parts CO2 by weight or lt or 12 percent ETO with nonflammable halogenated hydrocarbon refrigerant gases.   : United Kingdom Health & Safety Executive Studies have shown that chronic exposure to ethylene oxide increases the risk of cancer. Description of first aid measures First-aid measures general : IMPORTANT In all cases of exposure, get or summon medical treatment immediately. <>stream Geneva, World Health Organization (Environmental Health Criteria The EPA has set the upper level of acceptable cancer risk for polluted air at 1 in 100 in one million, or one in 10,000. life through disruptive products. Ethylene oxide (C₂H₄O) is a flammable gas with a somewhat sweet odor. For a single year of exposure to ethylene oxide, the cancer risk is greater for children than for adults. Permissible exposure limits — 1910.1047 (c) (1) 8-hour time weighted average (TWA). The PEL for ethylene oxide is set at one part of ethylene oxide per million parts of air (1 "part per million," or 1 "ppm"). Workers may be harmed from exposure to ethylene oxide. Workplace Exposure Monitoring. Except as limited by paragraph (f) of this section, each employer shall, upon request, assure the access to each employee and designated representative to employee exposure records relevant to the employee. <>stream hޜ�wTT��Ͻwz��0�z�.0��. For example, the used and reported detection limit for ethylene oxide in EHEC is, according to the petitioner, … Ethylene oxide . Ethylene oxide is produced in large volumes and is used to make other chemicals, especially ethylene glycol, a chemical used to make antifreeze and polyester. Corporations are required to adhere to emission limits. Corporations are required to adhere to emission limits. We build great products to solve your endstream Mixture Not applicable SECTION 4: First aid measures 4.1. Per the AAMI 10993-7 standard, “No exposure limits are set for ethylene glycol because risk assessment indicated that when EO residues are controlled, it is unlikely that biologically significant residues of EG would be present.” ��3�������R� `̊j��[�~ :� w���! Permissible Exposure Limit (PEL) for the amount of ethylene oxide in your workplace air. It dissolves easily in water, alcohol, and most organic solvents. Ethylene oxide is toxic by inhalation, with a US OSHA permissible exposure limit calculated as a TWA (time weighted average) over 8 hours of 1 ppm, and a short term exposure limit (excursion limit) calculated as a TWA over 15 minutes of 5 ppm. OSHA Permissible Exposure Limit (PEL) : 1.0 ppm (8 Hr TWA) -Duties: Employers have a duty to provide a safe work environment and employees have a duty to work safely. 7 0 obj $�TH�;Ԉvq�B�0d`s�2�aŦlR/Ob g����FI�e��(�r�cU���Z��7�7�n�5�m^�;M���}j��x�_UA��$�P���h��p�$���x�G��ԛ��x2��~���S��p������X8P$�'��4M��Ƽ��O$���q�\R�+��*+H�e���Ն�P�!a1"�*��$9n�b�Ӷ���h�uQ e0�Xv��܃�����T��e[>��E� b?J, As a basis for risk estimations for ethylene oxide (EtO) exposure and for the establishment of occupational exposure limits Date of issue: 01/01/1982 Revision date: 10/24/2016 Supersedes: 10/26/2015 EN (English US) SDS ID: P-4798 1/10 Sheikh K. The proposed revision of the US standard for occupational exposure to ethylene oxide has recently been topical and controversial. Ethylene oxide is flammable, colorless gas used to kill bacteria, fungi and fungal spores. Am J Ind Med. Methods and observations that may be used to detect the presence or release of a hazardous chemical in the work area (such as monitoring conducted by the employer, continuous monitoring devices, visual appearance or odor of hazardous chemicals when being released, etc. The hospital manages its hazardous materials and waste risks. Ethylene oxide is flammable within wide limits. The Committee has now been informed that the currently achievable detection limit for ethylene oxide is well below the specified purity criteria of 0.5 and 1.0 mg/kg. This is about equal to . In accordance with the OSHA standard, these records must be maintained by the health care facility for the duration of employment and for at least 30 years thereafter. Ethylene oxide (also known as ETO or oxirane) is a flammable gas with a somewhat sweet odor. : Association for the Advancement of Medical Instrument If EBX monitoring shows EtO levels exceeding the PEL or EL, corrective actions must be taken and documented, as required by OSHA. The primary routes of human exposure to ethylene oxide are inhalation and ingestion, which may occur through occupational, consumer, or environmental exposure. How is ethylene oxide regulated for worker safety? Inland Transport of Dangerous Goods Directive, Annex III ... Occupational exposure limits - Previous calls for comments and evidence; Occupational exposure limits – Consultations on OEL recommendation; Accordingly, at measured background levels of ethylene oxide, the EPA’s unit risk factor for lymphoid cancer (7.1E-03 per ppb, ADAF adjusted) would predict a population-weighted lymphoid cancer incidence rate of ≈3.7% (in the absence of any exogenous ethylene oxide ambient air exposure or other potential causes of lymphoid cancer). AAMI “Employee exposure record” means a record containing any of the following kinds of information: Environmental (workplace) monitoring or measuring of a toxic substance or harmful physical agent,…, Whenever an employee or designated representative requests access to a record, the employer shall assure that access is provided in a reasonable time, place, and manner…. UK HSE Long-Term This is determined as a time-weighted-average exposure over an eight- hour period. determinations of ethylene oxide concentrations in environmental air ranging from 0.11 to 12.3 ppm and in alveolar air from 0.03 to 3.8 ppm (Brugnone et al 1985, 1986). Workplace Exposure Limits OSHA: The legal airborne permissible exposure limit (PEL) is 1 ppm averaged over an 8-hour workshift and 5 ppm, as an excursion limit, averaged over a period of -minutes. : American Conference of Government Industrial Hygienist Also, records of monitoring results are required by OSHA. After years of extensive study, public input and peer review, TCEQ today finalized its updated safe exposure level for ethylene oxide. 1984;6(2):117-27. Scand J Work Environ Health 14 (1988) 372-377. 1.8 milligrams of ethylene oxide per cubic meter of air (1.8 "mg/m3"). endobj $E}k���yh�y�Rm��333��������:� }�=#�v����ʉe 29 CFR 1910.1200 Hazard Communication Standard, Requires chemical manufacturers or importers to classify the hazards of chemicals which they produce or import, Employers must provide information to their employees about the hazardous chemicals to which they are exposed, by means of a hazard communication program, labels and other forms of warning, safety data sheets, and information and training. �tq�X)I)B>==���� �ȉ��9. h��[K�@���W�c:����j[D���%ݴ�&�%���ܼ>� "H`�����$0g'$d ��H�R {'���\�� v" �:�K����I.��\¸���z4JCZ�������t��{��� Ethylene oxide, sold for fumigation or sterilization purposes, is often mixed with carbon dioxide (e.g., 10-30% ethylene oxide and 70-90% carbon dioxide) or fluorocarbons (e.g., 12% ethylene oxide and 88% fluorocarbons), as already indicated by the trade names in section 1.1. AAMI ST:41:1999 and ST:58:2013 [g(2)], Suppliers will provide with first shipment and shipments after SDS revision [g(6)], Employers shall provide employees with effective information and training on hazardous chemicals in their work area at the time of their initial assignment, and whenever a new chemical hazard the employees have not previously been trained about is introduced into their work area. Ethylene oxide . It is therefore necessary in many commercial applications to mix it with a nonflammable carrier. ETHYLENE OXIDE: ICSC: 0155: 1,2-Epoxyethane Oxirane Dimethylene oxide: July 2015: CAS #: 75-21-8: ... Explosive limits, vol% in air: 3-100 Octanol/water partition coefficient as log Pow: -0.3 EXPOSURE & HEALTH EFFECTS; Routes of exposure The substance can be absorbed into the body by inhalation and through the skin. Australian health authorities have set a maximum air concentration of ethylene oxide (averaged over a 40-hour week) for a workplace of 1800 micrograms per cubic metre of air (1 gram = 1,000,000 micrograms). of air/water or in the workplace where ethylene oxide is utilized – Amounts in food are low as ethylene oxide evaporates or breaks down shortly after fumigation • Regulatory and/or Published Limits – OSHA PEL (permissible exposure limit) = 1 ppm (averaged over an 8-hour workshift) = 1.8 mg/m3 = 18 mg/day [h(1)], If multiple employers, then must ensure that all employees potentially exposed to chemicals are trained [(2), Location of written plan, SDSs and chemical list. We are a team of passionate people whose goal is to improve everyone's The deadline for meeting the requirements of the state permit is December 18, 2019. Ethylene oxide, or EtO, is a gas at room temperature. (8 Hr TWA) TCEQ then used the standard approach for a chemical with this type of mode of action, which predicts a linear increase in cancer risks with increasing ethylene oxide exposure. UK HSE NIOSH REL — NIOSH’s recommended exposure limit; the recommended exposure limit for an 8- or 10-hour time- weighted average exposure and/or ceiling. The permit limits total facility emissions of ethylene oxide to 150 pounds per year. TCEQ and the EPA agree that this is ethylene oxide’s mode of action. Ethylene oxide is produced in large volumes and is used to make other chemicals, especially ethylene glycol, a chemical used to make antifreeze and polyester. 200-849-9 : 75-21-8 : Active: Full: Joint ≥ 1 000 000 tonnes : 04-12-2020: View substance registered dossier: Ethylene oxide . Employees must be notified of their personal monitoring results within 15 days of when the monitoring report is available, and a copy of the monitoring records must be kept in each employee’s file. These standards help ensure levels of ethylene oxide on medical devices are within safe limits since long-term and occupational exposure to ethylene oxide has been linked to cancer. Most ethylene oxide is used up in the factories where it is produced. Ethylene oxide emissions from industrial manufacturing and other applications are strictly regulated under federal and in some cases state and local laws. [b(1)]. 1.8 milligrams of ethylene oxide per cubic meter of air (1.8 "mg/m3"). Environmental and EBZ monitoring must be documented, and records maintained in the department files or another designated location. Ethylene oxide emissions from industrial manufacturing and other applications are strictly regulated under federal and in some cases state and local laws. Exposure limits and guidelines when using ethylene oxide have been set by a number of national agencies including the following: OSHA: Occupational and Safety Health Administration. The methods the employer will use to inform employees of the hazards of non-routine task, Trade secrets – information can be kept as trade secrets so long as safety information is not withheld and composition is made available in case of emergency. Environmental and employee monitoring/Recordkeeping. If environmental monitoring results are posted, workers will know that potentially dangerous concentrations of PAA could exist in the workplace, and the importance of proper work practices will be reinforced. Standard pictograms indicating chemical hazards have been developed under the Globally Harmonized System of Classification and Labeling of Chemicals (GHS);2 some of which are shown below. Ethylene oxide, called oxirane by IUPAC, is an organic compound with the formula C 2 H 4 O.It is a cyclic ether and the simplest epoxide: a three-membered ring consisting of one oxygen atom and two carbon atoms.Ethylene oxide is a colorless and flammable gas with a faintly sweet odor. ); The physical, health, simple asphyxiation, combustible dust, and pyrophoric gas hazards, as well as hazards not otherwise classified, of the chemicals in the work area. The hospital creates and maintains an inventory that identifies hazardous materials and waste used, stored, or generated using criteria consistent with applicable law and regulation (for example, the Environmental Protection Agency [EPA] and the Occupational Safety and Health Administration [OSHA]). What limits of human exposure to ethylene oxide have been set? The PEL for ethylene oxide is set at one part of ethylene oxide per million parts of air (1 "part per million," or 1 "ppm"). Basis for original (SCP) IDLH: The chosen IDLH is based on the statement by AIHA that the estimated LC 50 for a 4-hour exposure is approximately 800 to 1,500 ppm depending on the species [Jacobson et al. The results of environmental monitoring should be posted in an area that is readily accessible to employees. Most ethylene oxide is used up in the factories where it is produced. NIOSH Immediately Dangerous to Life and Health (IDLH), : American Conference of Government Industrial Hygienist, : Association for the Advancement of Medical Instrument, : United Kingdom Health & Safety Executive. Exposure limits and guidelines when using ethylene oxide have been set by a number of national agencies including the following: OSHA: Occupational and Safety Health AdministrationOSHA Permissible Exposure Limit (PEL) :  1.0 ppm (8 Hr TWA)    -Duties: Employers have a duty to provide a safe work     environment and employees have a duty to work safely. Also, if the posted results show that all areas and occupations are below the action level, employees will be encouraged to continue the safe practices that made this possible. OSHA established a A permissible limit for occupational exposure to EtO, which is one part EtO per one million parts of air (1 ppm).' People who live and work near manufacturing plants who release ethylene oxide into the air are at risk for ethylene oxide exposure (“ETO”) and contamination. ETHYLENE OXIDE Please note that the ... from exposure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, ... guidance values for health-based exposure limits. :  1.0 ppm  $O./� �'�z8�W�Gб� x�� 0Y驾A��@$/7z�� ���H��e��O���OҬT� �_��lN:K��"N����3"��$�F��/JP�rb�[䥟}�Q��d[��S��l1��x{��#b�G�\N��o�X3I���[ql2�� �$�8�x����t�r p��/8�p��C���f�q��.K�njm͠{r2�8��?�����. %PDF-1.4 The hospital maintains documentation, including required permits, licenses, and adherence to other regulations. The threshold limit for continuous daily breathing is presently listed by the American Conference of Governmental Industrial Hygienists (ACGIH, 1981) for change from 10 to 5 ppm. It dissolves easily in water, alcohol, and most organic solvents. It is not necessary to base the EtO alarm trigger specifically on the OSHA action level (0.5 ppm) or permissible exposure limits for 8 hours (1 ppm) or 15 minutes (5 ppm). Ensure the Safety and Health of all people potentially exposed to hazardous chemical vapors in the workplace. Ethylene Oxide may polymerize (self-react) violently. Exposure to ethylene oxide can occur through inhalation or skin-contact.   The measures employees can take to protect themselves from these hazards, including specific procedures the employer has implemented to protect employees from exposure to hazardous chemicals, such as appropriate work practices, emergency procedures, and personal protective equipment to be used; and. The primary routes of human exposure to ethylene oxide are inhalation and ingestion, which may occur through occupational, consumer, or environmental exposure. Exposure records to the extent necessary to reasonably indicate the amount and nature of the toxic substances or harmful physical agents at workplaces or under working conditions to which the employee is being assigned or transferred.   Clip the monitoring badge … Rationale: Good record keeping enables the health care facility to establish a continuous history of the work environment. 200-849-9 : 75-21-8 : Active: Full: Joint ≥ 1 000 000 tonnes : 04-12-2020: View substance registered dossier: Ethylene oxide . Standard Includes the following requirements: Include Product identifier, hazard statements, pictogram, precautionary statements, name & address of manufacturer or responsible party. 1. OSTERMAN-GOLKAR S, BERGMARK E. Occupational exposure to ethylene oxide: Relation between in vivo dose and exposure dose. Qf� �Ml��@DE�����H��b!(�`HPb0���dF�J|yy����ǽ��g�s��{��. In addition, OSHA identified an action-level exposure of 0.05 ppm, averaged over an eight-hour period. EtO brings serious risks of chemical burns to body tissues if a device, such as a plastic or rubber face mask, sterilized in EtO is not aerated (aeration cycle) after the sterilization cycle to allow the EtO absorbed during the cycle to elute from the mask, is … )ɩL^6 �g�,qm�"[�Z[Z��~Q����7%��"�   Measurement of personal exposure is very easy. [f(1)], Labels not required for portable containers for immediate use [f(8)], Labels shall be in English and optionally also in other languages if spoken by workers, Maintain for all chemicals in the workplace and accessible to workers [g(8)], Sections include: Identification, Hazard Identification, Composition, First Aid Measures, Fire fighting Measures, Accidental Release Measures, Handling & Storage, Exposure Controls & Personal Protection, Physical & Chemical Properties, Stability and Reactivity, Toxicology, Ecological Information, Disposal, Transportation, Regulations, Other Information including date of last revision. [i]. Under the Clean Air Act, the EPA has set emission standards for 187 different toxic air pollutants, including ethylene oxide. OSHA has set exposure limits for employees working in facilities where ethylene oxide gas is present. Permissible Exposure Limit (PEL) for the amount of ethylene oxide in your workplace air. their performance. business problems. -Hazard Communication Regulation, suppliers (labels,     safety data sheets), Employers (facilities, work practices,     training and personal protective equipment) to enable     the safe use of the chemicalsNIOSH: National Institute of Occupational Safety and HealthNIOSH Immediately Dangerous to Life and Health (IDLH) :  800 ppmJC: Joint CommissionJoint Commission Standard EC.02.02.01, ACGIH   Talk to a ChemDAQ Technical Sales Representative today. 1956]. 1970 Occupational Health & Safety Act created the Occupational Safety and Health Administration (OSHA) and empowered OSHA to create and enforce workplace safety standards. How is ethylene oxide regulated for worker safety? This is because ethylene oxide can damage DNA. For the purpose of this section, an exposure record relevant to the employee consists of: A record which measures or monitors the amount of a toxic substance or harmful physical agent to which the employee is or has been exposed; In the absence of such directly relevant records, such records of other employees with past or present job duties or working conditions related to or similar to those of the employee to the extent necessary to reasonably indicate the amount and nature of the toxic substances or harmful physical agents to which the employee is or has been subjected, and.   Ethylene oxide directly interacts with DNA to cause damage that can lead to mutations and cancer. Because ethylene oxide is highly explosive and reactive, the equipment used for its processing generally consists of tightly closed and highly automated systems, which decreases the risk of occupational exposure. Details of the hazard communication program developed by the employer, including an explanation of the labels received on shipped containers and the workplace labeling system used by their employer; the safety data sheet, including the order of information and how employees can obtain and use the appropriate hazard information. Oxide what is ethylene oxide ( also known as ETO or oxirane ) a..., fungi and fungal spores a team of passionate people whose goal is to improve life. And fungal spores Active: Full: Joint ≥ 1 000 000 tonnes: 04-12-2020: View substance dossier! Basic information about ethylene oxide has recently been topical and controversial review, tceq today finalized its safe. Has set exposure limits — 1910.1047 ( c ) ( Main constituent ) 75-21-8 100 3.2 another designated.! Cubic meter of air ( 1.8 `` mg/m3 '' ) C₂H₄O ) is a large range in the factories it! Should be posted in an area that is readily accessible to employees is determined as a exposure... 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For meeting the requirements of the state permit is December 18, 2019 EBZ monitoring must be documented as.

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